(4S )-(+)- phényl - alpha-[( 4S)- phenyloxazolidin- 2 - ylidene]-2 - oxazoline - 2 - acétonitrile, 97 %

Code: 417068-1G D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile/Re(V)-oxo complex can catalyze the asymmetric hydrosilylation of ...


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Votre prix
$450.98 1G
DEMANDER

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile/Re(V)-oxo complex can catalyze the asymmetric hydrosilylation of ketones.

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

General description

(4S)-(+)-Phenyl-A-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.

Packaging

1 g in glass bottle

assay97%
formsolid
InChI keyQVVGSAYHUSBCQV-SRKGJJLTSA-N
InChI1S/C20H17N3O2/c21-11-16(19-22-17(12-24-19)14-7-3-1-4-8-14)20-23-18(13-25-20)15-9-5-2-6-10-15/h1-10,17-18,22H,12-13H2/b19-16-/t17-,18-/m1/s1
mp146-148 °C (lit.)
optical activity[α]20/D +364°, c = 1 in chloroform
SMILES stringN#CC(=C1N[C@H](CO1)c2ccccc2)C3=N[C@H](CO3)c4ccccc4
Cas Number150639-33-1
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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