(4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile, 97%

Code: 417068-1G D2-231

Not available outside of the UK & Ireland.

Application

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile/Re(V)-oxo complex can catalyze the asymmetric hydrosilylation of ...


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$450.98 1G
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Not available outside of the UK & Ireland.

Application

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile/Re(V)-oxo complex can catalyze the asymmetric hydrosilylation of ketones.

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

General description

(4S)-(+)-Phenyl-A-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.

Packaging

1 g in glass bottle

assay97%
formsolid
InChI keyQVVGSAYHUSBCQV-SRKGJJLTSA-N
InChI1S/C20H17N3O2/c21-11-16(19-22-17(12-24-19)14-7-3-1-4-8-14)20-23-18(13-25-20)15-9-5-2-6-10-15/h1-10,17-18,22H,12-13H2/b19-16-/t17-,18-/m1/s1
mp146-148 °C (lit.)
optical activity[α]20/D +364°, c = 1 in chloroform
SMILES stringN#CC(=C1N[C@H](CO1)c2ccccc2)C3=N[C@H](CO3)c4ccccc4
Cas Number150639-33-1
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