Chlorodicyclopentylphosphine, 97 %

Code: 649066-5g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Chlorodicyclopentylphosphine may be used to prepare:Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol](S

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Votre prix
$273.28 5G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Chlorodicyclopentylphosphine may be used to prepare:Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol](S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinoneLcPeNiCl, a precursor for preparing LcPeNiH, which is an efficient catalyst for the reduction of CO2[cPe=cyclopentyl]

General description

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.

http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf

Packaging

5 g in glass bottle

assay97%
density1.069 g/mL at 25 °C (lit.)
functional groupphosphine
InChI keyQTYRJBRBODDGCQ-UHFFFAOYSA-N
InChI1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligand
SMILES stringClP(C1CCCC1)C2CCCC2
Cas Number130914-24-8
Hazard Class8
Un Number3265
Pack Group2
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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