2-(Trimethylsiloxy)-1,3-cyclohexadiene, 95%

Code: 423424-5ML D2-231

Not available outside of the UK & Ireland.

Application

2-(Trimethylsiloxy)-1,3-cyclohexadiene may be used as a diene in the synthesis of isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione by reacting with p-toluene...


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$112.95 5ML
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Not available outside of the UK & Ireland.

Application

2-(Trimethylsiloxy)-1,3-cyclohexadiene may be used as a diene in the synthesis of isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione by reacting with p-toluenesulfonyl cyanide.

General description

2-(Trimethylsiloxy)-1,3-cyclohexadiene ((cyclohexa-1,5-dien-1-yloxy)trimethylsilane) is silyl enol ether of cyclohexenone. The Diels–Alder reactions with dienophiles α-acetoxyacrylonitrile, acrylonitrile and α-chloroacrylonitrile has been studied.

Packaging

5, 25 mL in glass bottle

assay95%
bp65 °C/7 mmHg (lit.)
density0.899 g/mL at 25 °C (lit.)
formliquid
InChI keyWPIRVUXAMPRMAY-UHFFFAOYSA-N
InChI1S/C9H16OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h5,7-8H,4,6H2,1-3H3
Quality Level100
refractive indexn20/D 1.462 (lit.)
SMILES stringC[Si](C)(C)OC1=CCCC=C1
storage temp.2-8°C
Cas Number54781-19-0
Hazard Class3
Un Number1993
Pack Group3
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