Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-alpha,alpha,alpha,alpha-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium, 97%

Code: 449520-100MG D2-231

Not available outside of the UK & Ireland.

Application

A novel highly enantioselective allyl-transfer reagent. Excellent regio-, diastereo-, and enantioselectivities (usually >95% ee, >95% de) are obtained for the add...


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$92.76 100MG
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Not available outside of the UK & Ireland.

Application

A novel highly enantioselective allyl-transfer reagent. Excellent regio-, diastereo-, and enantioselectivities (usually >95% ee, >95% de) are obtained for the addition of allyl nucleophiles to aldehydes.

Packaging

100 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

assay97%
InChI keyLTNGUQMGXWBBMV-CRMRIEQBSA-M
InChI1S/C31H30O4.C5H5.ClH.Ti/c1-29(2)34-27(30(32,23-15-7-3-8-16-23)24-17-9-4-10-18-24)28(35-29)31(33,25-19-11-5-12-20-25)26-21-13-6-14-22-26;1-2-4-5-3-1;;/h3-22,27-28,32-33H,1-2H3;1-5H;1H;/q;;;+1/p-1/t27-,28-;;;/m1.../s1
mp209-213 °C (lit.)
optical activity[α]20/D -246°, c = 1 in chloroform
Quality Level200
SMILES stringCl[Ti].[CH]1[CH][CH][CH][CH]1.CC2(C)O[C@H]([C@@H](O2)C(O)(c3ccccc3)c4ccccc4)C(O)(c5ccccc5)c6ccccc6
Cas Number132068-98-5
Hazard Class8
Un Number3261
Pack Group2
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