2,2 - diméthylcyclopentanone, 96 %

Code: 371475-5g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

2,2-Dimethylcyclopentanone enolate may be used as starting reagent in the enantioselective synthesis of chiral phosphines belonging to the P-aryl-2-phosphabicyclo...


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Votre prix
$236.93 5G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

2,2-Dimethylcyclopentanone enolate may be used as starting reagent in the enantioselective synthesis of chiral phosphines belonging to the P-aryl-2-phosphabicyclo[3.3.0]octane family (PBO). It may be used in the synthesis of:2,6,6-trimethyl-2-azaspiro[4.4]nonane-1,3-dione, a spirosuccinimide moiety of asperparaline Anovel spiropentanopyrrolizidine oxime alkaloids, namely 2′,3′,5′,6′,7′,7a′-hexahydro-2,2-dimethylspirocyclopentane-1δ,δ-dimethyl-δ-valerolactone, via Baeyer-Villiger oxidation

General description

2,2-Dimethylcyclopentanone is a ketone. Synthesis of various C-2 substituted vitamin D derivatives with a 2,2-dimethylcyclopentanone unit in side chains has been reported. Regioselective synthesis of 2,2-dimethylcyclopentanone, via its enolate precursor regioselectively obtained using the 2-pyrrolidone magnesium salt, has been reported.

Packaging

1, 5 g in glass bottle

assay96%
bp143-145 °C (lit.)
density0.894 g/mL at 25 °C (lit.)
InChI keyFTGZMZBYOHMEPS-UHFFFAOYSA-N
InChI1S/C7H12O/c1-7(2)5-3-4-6(7)8/h3-5H2,1-2H3
Quality Level200
refractive indexn20/D 1.433 (lit.)
SMILES stringCC1(C)CCCC1=O
Cas Number4541-32-6
Hazard Class3
Un Number1224
Pack Group3
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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