JackiePhos, 95 %

Code: 731013-100MG D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Catalyst for N-Arylation reactionsBuchwald Phosphine Ligands for chemical Synthesis

JackiePhos is a Buchwald′s phosphine ligand which can be used f...


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Votre prix
$145.39 100MG

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Catalyst for N-Arylation reactionsBuchwald Phosphine Ligands for chemical Synthesis

JackiePhos is a Buchwald′s phosphine ligand which can be used for the:glycosyl cross-coupling reaction of diaryliodonium triflates with anomeric stannanes to synthesize C-glycosides.synthesis of gold-based catalyst complexes such as [Au(CH3CN)(JackiePhos)][SbF6] and [(JackiePhos)AuCl.acylation of alkylcarbastannatranes.synthesis of cyclic guanidines or cyclic ureas bearing dialkylaminomethyl groups in combination with Pd(acac)2 as a catalyst.

Packaging

100, 250 mg in glass bottle

1 g in glass bottle

assay95%
formsolid
functional groupphosphine
InChI keyKYTUFIMHJNRPLC-UHFFFAOYSA-N
InChI1S/C39H37F12O2P/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51/h9-21H,1-8H3
mp186-190 °C
Quality Level100
reaction suitabilityreagent type: ligandreaction type: C-X Bond Formation, reagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings
SMILES stringCOc1ccc(OC)c(c1P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
Cas Number1160861-60-8
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