Triméthylphosphine, 97 %

Code: 323322-25G D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Trimethylphosphine (PMe3) is an electron-rich phosphine ligand used as a reagent in Mitsunobu reaction.It can be used:In transformation of azides into ...


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Votre prix
$667.72 25G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Trimethylphosphine (PMe3) is an electron-rich phosphine ligand used as a reagent in Mitsunobu reaction.It can be used:In transformation of azides into carbamates; aziridines to azidoalcohols; and ketoximes to ketones with 2,2′-dipyridyl diselenide.In Aza-Wittig reaction;, C-H bond activation of imines; cross-coupling reactions.In the preparation of (cyanomethylene) trimethylphosphorane (CMMP) which is used as a reagent in Mitsunobu type reaction.As a reagent in the synthesis of ruthenium trimethylphosphine complexes, which in turn are used as catalysts for hydrogenation of CO2 to formic acid.

Packaging

25 g in Sure/Seal™

assay97%
bp38-40 °C (lit.)
density0.738 g/mL at 20 °C (lit.)
formliquid
functional groupphosphine
InChI keyYWWDBCBWQNCYNR-UHFFFAOYSA-N
InChI1S/C3H9P/c1-4(2)3/h1-3H3
mp−86 °C (lit.)
Quality Level200
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reagent type: ligandreaction type: Mitsunobu Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligandreaction type: Wittig Reaction
refractive indexn20/D 1.428 (lit.)
SMILES stringCP(C)C
storage temp.2-8°C
vapor pressure7.24 psi ( 20 °C)
Cas Number594-09-2
Hazard Class3
Un Number1993
Pack Group2
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