XPhos Pd G3, 95%

Code: 763381-1g D2-231

Not available outside of the UK & Ireland.

Application

XPhos Pd G3 may be used in the following reactions: Cyanation reaction of heterocyclic halides.Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents....


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$259.82 1G
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Not available outside of the UK & Ireland.

Application

XPhos Pd G3 may be used in the following reactions: Cyanation reaction of heterocyclic halides.Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents. Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.

General description

XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

assay98%
featuregeneration 3
formsolid
functional groupphosphine
InChI keyNKKHABPORDUWIG-UHFFFAOYSA-M
InChI1S/C33H49P.C12H10N.CH4O3S.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
mp146-151 °C (decomposition)
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystreaction type: Cross Couplings
SMILES stringCC(C1=CC(C(C)C)=C(C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C(C)C)=C1)C.NC5=C(C=CC=C5)C6=C(C=CC=C6)[Pd]OS(C)(=O)=O
Cas Number1445085-55-1
This product has met the following criteria to qualify for the following awards:



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