Chlorure d'étain (IV), 98 %

Code: 208930-250G D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Stannic chloride can be used to catalyze:Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.Formation of C-glycosides of aromatic ...


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Votre prix
$86.02 250G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Stannic chloride can be used to catalyze:Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.Other applications of SnCl4:The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.

General description

Stannic chloride (SnCl4) is a strong Lewis acid widely used as a promoter or catalyst in organic synthesis. It is soluble in most organic solvents.

Packaging

2 kg in Sure/Seal™

250 g in Sure/Seal™

assay98%
bp114 °C (lit.)
density2.226 g/mL at 25 °C (lit.)
formliquid
InChI keyHPGGPRDJHPYFRM-UHFFFAOYSA-J
InChI1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
mp−33 °C (lit.)
Quality Level200
reaction suitabilityreagent type: Lewis acid, core: tin, reagent type: catalyst
SMILES stringCl[Sn](Cl)(Cl)Cl
vapor density9 (vs air)
vapor pressure20 mmHg ( 22 °C), 18.6 mmHg ( 20 °C), 10 mmHg ( 10 °C)
Cas Number7646-78-8
Hazard Class8
Un Number1827
Pack GroupII
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