N-Boc-pyrrole, 98%

Code: 425834-25ml D2-231

Not available outside of the UK & Ireland.

Application

N-Boc-pyrrole was used in the synthesis of 1-(tert-butoxycarbonyl)-1H-pyrrol-2-ylboronic acid by treating with n-BuLi and subs...


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Your Price
$55.83 25ML

Not available outside of the UK & Ireland.

Application

N-Boc-pyrrole was used in the synthesis of 1-(tert-butoxycarbonyl)-1H-pyrrol-2-ylboronic acid by treating with n-BuLi and subsequent reaction with trimethyl borate.It may be used as starting material in the synthesis of the following:tropane drivativesN-boc-2-(4-methoxyphenyl)pyrroleN-boc-pyrrol-2-ylboronic acid

General description

N-Boc-pyrrole is an N-protected pyrrole. It undergoes Diels–Alder reaction with enantiomerically pure allene-1,3-dicarboxylates to form endo-adducts with retention in configurations at two newly generated stereogenic centers. It also undergoes cyclopropanation with methyl phenyldiazoacetate to form both monocyclopropane and dicyclopropane. Its Ir-catalyzed C-H borylation followed by cross coupling with 3-chlorothiophene to form biheterocycle has been reported.

Packaging

25, 100 mL in poly bottle

assay98%
bp91-92 °C/20 mmHg (lit.)
density1 g/mL at 25 °C (lit.)
formliquid
InChI keyIZPYBIJFRFWRPR-UHFFFAOYSA-N
InChI1S/C9H13NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H,1-3H3
Quality Level100
refractive indexn20/D 1.4685 (lit.)
SMILES stringCC(C)(C)OC(=O)n1cccc1
Cas Number5176-27-2
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