S)-SIPHOS - PE,97 %

Code: 700762-250MG D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize: Spiroindolenines by Pd-catalyzed intramolecular dearomative aryla...


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Votre prix
$646.18 250MG

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize: Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles. Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones. Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.

Packaging

50, 250 mg in amber glass bottle

assay97%
formpowder
InChI keyZXLQLIDJAURBDD-HRPAVAKOSA-N
InChI1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1
mp120-125 °C
optical activity[α]22/D −65.0°, c = 1 in chloroform
Quality Level100
SMILES stringC[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7
storage temp.−20°C
Cas Number500997-70-6
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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