-BINAP,

Code: 693065-100MG D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst,...


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Votre prix
$37.83 100MG
DEMANDER

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst, which can catalyze the asymmetric allylation of 1,3-diketones to form chiral 2,2-dialkyl-1,3-diketones. It may also be used in the preparation of chirally stabilized rhodium nanoparticles, which can be used as a catalyst for the asymmetric hydroformylation of styrene and vinyl acetate.

Legal Information

Sold in collaboration with Takasago for research purposes only.

Packaging

100, 500 mg in amber glass bottle

formcrystals
InChI keyMUALRAIOVNYAIW-UHFFFAOYSA-N
InChI1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
mp239-241 °C (lit.)
optical activity[α]20/D +222°, c = 0.5% in benzene
Quality Level100
SMILES stringc1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
Cas Number76189-55-4
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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