O-Allyl - n -( 9 - anthracenylméthyl) bromure de cinchonidinium, 90 %

Code: 499617-1G D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schif...


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Votre prix
$146.74 1G
DEMANDER

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.

General description

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.

Packaging

1, 5 g in glass bottle

assay90%
InChI keyQOWNPAUSLGATNL-JNKXQCINSA-M
InChI1S/C37H37N2O.BrH/c1-3-21-40-37(33-17-19-38-35-16-10-9-15-32(33)35)36-23-27-18-20-39(36,24-26(27)4-2)25-34-30-13-7-5-11-28(30)22-29-12-6-8-14-31(29)34;/h3-17,19,22,26-27,36-37H,1-2,18,20-21,23-25H2;1H/q+1;/p-1/t26-,27-,36-,37+,39?;/m0./s1
mp170 °C (dec.) (lit.)
optical activity[α]20/D −345±30°, c = 0.45 in chloroform
Quality Level100
SMILES string[Br-].[H][C@@]12CC[N+](C[C@@H]1C=C)(Cc3c4ccccc4cc5ccccc35)[C@@]([H])(C2)[C@H](OCC=C)c6ccnc7ccccc67
Cas Number200132-54-3
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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