-(+)-(6,6-Dimethoxybiphenyl-2,2-diyl)bis(diphenylphosphine), >=97%, optical purity ee: >=99%

Not available outside of the UK & Ireland.

Application

Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines; the Ru(II) complex hydrogenates ß-keto esters in high enantioselectivity; the Pd(0) complex for cyclization of hydroxy allylic carbonates.

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Atropisomeric MeOBIPHEP ligands Hydrogenation of α- and β-functionalized ketones Hydrogenation of heteroarenes C–C coupling reactions

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

sold in collaboration with Solvias AG

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.