Cyanoformate éthylique, 99 %

Code: E18859-50G D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Ethyl cyanoformate can be used as a cyanide source for the cyanation of:Activated olefins in the presence of a titanium catalyst.Carbonyl compounds catalyzed by 4...


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Votre prix
$297.51 50G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Ethyl cyanoformate can be used as a cyanide source for the cyanation of:Activated olefins in the presence of a titanium catalyst.Carbonyl compounds catalyzed by 4-dimethylaminopyridine (DMAP) to yield corresponding cyanohydrin carbonates under metal-free and solvent-free conditions.Aldehydes and 2,2,2-trifluoroacetophenone catalyzed by N-heterocyclic carbene (NHC) to yield corresponding cyanohydrins ethyl carbonates.

Ethyl cyanoformate is a general cyanating agent. It can be used in the nucleophilic addition of cyanide to carbonyl compounds, oxidative cyanation of tertiary amines and in the synthesis of β-cyano-substituted acrylates from alkynes.

Packaging

10, 50 g in glass bottle

assay99%
bp115-116 °C (lit.)
density1.003 g/mL at 25 °C (lit.)
formliquid
InChI keyMSMGXWFHBSCQFB-UHFFFAOYSA-N
InChI1S/C4H5NO2/c1-2-7-4(6)3-5/h2H2,1H3
Quality Level100
refractive indexn20/D 1.381 (lit.)
SMILES stringCCOC(=O)C#N
Cas Number623-49-4
Hazard Class6.1
Un Number3275
Pack GroupII
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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