(tert-Butyldimethylsilyl)acetylene, 99%

Code: 399264-1g D2-231

Not available outside of the UK & Ireland.

Application

(tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes.

General description

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Your Price
$99.01 1G

Not available outside of the UK & Ireland.

Application

(tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes.

General description

(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.

(tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes.

Packaging

1, 5 g in ampule

assay99%
bp116-117 °C (lit.)
density0.751 g/mL at 25 °C (lit.)
InChI keyRTYNRTUKJVYEIE-UHFFFAOYSA-N
InChI1S/C8H16Si/c1-7-9(5,6)8(2,3)4/h1H,2-6H3
Quality Level100
refractive indexn20/D 1.451 (lit.)
SMILES stringCC(C)(C)[Si](C)(C)C#C
Cas Number86318-61-8
Hazard Class3
Un Number1993
Pack GroupII
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