SPhos Pd G2,

Code: 753009-5g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Application in Suzuki-Miyaura coupling:Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.Suzuki–Miyaura coup...


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Votre prix
$794.26 5G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Application in Suzuki-Miyaura coupling:Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

featuregeneration 2
formsolid
functional groupphosphine
InChI keyNOMWEFBAPVZIIP-UHFFFAOYSA-M
InChI1S/C26H35O2P.C12H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
mp218 °C (dec.)
Quality Level100
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalystreaction type: Cross Couplings
SMILES stringCOC1=CC=CC(OC)=C1C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2.NC5=C(C6=C([Pd]Cl)C=CC=C6)C=CC=C5
Cas Number1375325-64-6
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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