S)-1-{(SP)-2 -[ 2 -( Diphenylphosphino) phényl]ferrocenyl} éthylbis [3,5-bis - (trifluorométhyl)] phosphore,>=97 %

Code: 65672-500mg D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine can be used: To prepare sulfide-capped triruthe...


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Votre prix
$440.06 500MG

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine can be used: To prepare sulfide-capped triruthenium hydrido clusters containing Walphos ligands, which are employed as catalysts for asymmetric hydrogenation of tiglic acid (trans-2-methyl-2-butenoic acid). As a ligand in the reductive allylic alkylation of unsaturated carbonyl compounds using Pd catalyst.

General description

sold in collaboration with Solvias AG

Packaging

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

1, 5 g in glass bottle

assay≥97%
InChI keyLKNKYBWIZNAXBY-KHZPMNTOSA-N
InChI1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m1../s1
optical purityee: ≥99%
Quality Level100
SMILES string[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
Cas Number849925-17-3
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