Non disponible en dehors du Royaume-Uni et de l'Irlande
Application
Aminosupersilane has been demonstrated by the MacMillan lab to be a necessary reagent in the dual catalytic nickel/photoredox cross-electrophile coupling of unactivated alkyl chlorides. The increased nucleophilicity of aminosupersilane, as compared to other organosilane reagents, is key to activating the alkyl chloride for chlorine atom abstraction.
Other Notes
Cross-Electrophile Coupling of Unactivated Alkyl Chlorides
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :