CIS-[2.2-BIS(diphénylphosphino)-1,1 - B

Code: 901166-100mg D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst wil...


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Votre prix
$173.66 EACH
DEMANDER

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.

Legal Information

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

Other Notes

Technology Spotlight: Jamison Nickel (II) Precatalysts A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

formpowder or solid
mp>300 °C
Quality Level100
reaction suitabilitycore: nickel, reagent type: catalyst
SMILES stringCl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
Cas Number1594113-05-9
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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