solution de chlorure de tert - butylmagnésium, 1,0 m dans le pouce

Code: 364649-800ml D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

tert-Butylmagnesium chloride (1.0 M in THF) has been used in the preparation of tert-butylsulfinyl chloride. It can be used in: Grignard metathe...


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Votre prix
$539.83 EACH

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

tert-Butylmagnesium chloride (1.0 M in THF) has been used in the preparation of tert-butylsulfinyl chloride. It can be used in: Grignard metathesis reaction of 2,5-dibromo-3-hexylthiophene to form 2-bromo-5-magnesiobromo-3-hexylthiophene.A key step for the asymmetric synthesis of sulfinyl transfer agents using cinchona alkaloids quinine and quinidine as chiral auxiliaries.

General description

tert-Butylmagnesium chloride, an organomagnesium compound, is commonly known as Grignard reagent. It is a powerful carbon nucleophile mainly used for C-C bond formation.

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and ocassional gentle swirling should redissolve the solid.

Packaging

100, 800 mL in Sure/Seal™

concentration1.0 M in THF
density0.931 g/mL at 25 °C
InChI keyZDRJSYVHDMFHSC-UHFFFAOYSA-M
InChI1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
Quality Level200, 100
reaction suitabilityreaction type: Grignard Reaction
SMILES stringCC(C)(C)[Mg]Cl
Cas Number677-22-5
Hazard Class4.3
Un Number3399
Pack Group1
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



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