(4)-2-[ 2 -( diphénylphosphino) phénol] -4,5 - dihydro - 5,5 - diméthyl- 4 -(1 - méthylethyl)- oxazole,97 %

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-Bu-PHOX in Asymmetric CatalysisDesign, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates

(S)-5,5-(Dimethyl)-i-Pr-PHOX is a phosphinooxazoline ligand (PHOX), belongs to the class of non-C₂ symmetric chiral ligand. It can be used in: The enantioselective Pd-catalyzed allylation reactions. The synthesis of (R)-2-phenyl-2,5-dihydrofuran by the enantioselective Heck reaction between 2,3-dihydrofuran and phenyl triflate. The allylation reaction of fluorinated allyl enol carbonates and fluorinated silyl enol ethers to prepare allylated tert α-fluoroketones.

Packaging

500 mg in glass bottle