-(+)-2-méthyl - 2-propanesulfinē,98 %

Code: 497401-5g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(R)-(+)-2-Methyl-2-propanesulfinamide may be used to prepare N-(1-cyclohexylmethylidene)-2-methylpropane-2-sulfinamide via copper mediated conde...


 En savoir plus

Votre prix
$184.43 5G

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(R)-(+)-2-Methyl-2-propanesulfinamide may be used to prepare N-(1-cyclohexylmethylidene)-2-methylpropane-2-sulfinamide via copper mediated condensation with cyclohexane carboxaldehyde. It may also be used to prepare (20E)-N-[t-butyl-(R)-sulfinyl]-3β-(t-butyldimethylsilyloxy)-pregn-5-en-20-imine, an intermediate for the development of androgen receptor antagonists.

Ellman′s Sulfinamides

Useful reagent for synthesizing chiral amines.

Preparation of ß-chloro sulfinamides in a synthesis of chiral azridines. Also used to prepare an organocatalyst for enantioselective reduction of imines.

Can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.

Packaging

1, 5, 25 g in poly bottle

assay98%
InChI keyCESUXLKAADQNTB-SSDOTTSWSA-N
InChI1S/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/m1/s1
mp103-107 °C (lit.)
optical activity[α]20/D +4°, c = 1.0242 in chloroform stab. with amylenes
Quality Level100
SMILES stringCC(C)(C)S(N)=O
storage temp.2-8°C
Cas Number196929-78-9
Ce produit répond aux critères suivants pour être admissible aux récompenses suivantes :



HAVE AN ACCOUNT? LOGIN

GUEST CHECKOUT

Proceed as a guest. You will have the option to register to access exclusive pricing and stock availability features after checkout.