RH2 (R - PTAD)4

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control.

Other Notes

Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid ReactionsAsymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] CycloadditionAsymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E